A highly selective electron affinity facilitated H2S sensor: the marriage of tris(keto-hydrazone) and an organic field-effect transistor

Sa. Yuvaraja, V. Nagarajappa Bhyranalyar, S. A. Bhat, S. G. Surya, C. V. Yelamaggad, K. N.Salama
Mater. Horiz., 2021, Advance Article, (2021)

Keywords

Gas-sensing applications, Polymermonomer heterostructure, H2S gas

Abstract

​Conjugated polymers (CPs) are emerging as part of a promising future for gas-sensing applications. However, some of their limitations, such as poor specificity, humidity sensitivity and poor ambient stability, remain persistent. Herein, a novel combination of a polymer–monomer heterostructure, derived from a CP (PDVT-10) and a newly reported monomer [tris(keto-hydrazone)] has been integrated in an organic field-effect transistor (OFET) platform to sense H2S selectively. The hybrid heterostructure shows an unprecedented sensitivity (525% ppm−1) and high selectivity toward H2S gas. In addition, we demonstrated that the PDVT-10/tris(keto-hydrazone) OFET sensor has the lowest limit of detection (1 ppb), excellent ambient stability (∼5% current degradation after 150 days), good response–recovery behavior, and exceptional electrical behavior and gas response reproducibility. This work can help pave the way to incorporate futuristic gas sensors in a multitude of applications.

Code

DOI: https://doi.org/10.1039/D0MH01420F

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